Hi Jessica,
To aggregate strings, you should use the STUFF command (see how here).
ON your example, it would be something like this
SELECT
STUFF((
SELECT ',' + {Group}.[Description]
FROM
{Group_User}
LEFT JOIN {Group} R ON {Group_User
}.[Group_Id] = {Group}.[Id]
FOR XML PATH('')), 1, 1, '')
Cheers,
João Marques