Hi Dus,
Are you able to retrieve more details on the error you're getting?
Have you inspected the issue on Service Center console > Error Logs and then on that specific error accessing the Details page?
If necessary, you can try
auditing inside the SForce.xif extension to see what the problem is, to read the whole exception stack trace, for example.
Also, can your server access the Salesforce.com API endpoint? Looking into the SForce.xif extension, the web reference is using
https://login.salesforce.com/services/Soap/u/25.0 Can you test if this endpoint is reachable from the server having this issue?
Let us know how these suggestion work for you please, so we can help you further.
Regards,
Pedro